Preheat the oven to 350 degrees, grease and flour three 8x2 inch round pans
In a medium bowl, whisk the flour, cocoa, baking powder, and baking soda. Set aside
In another bowl, add the buttermilk, Baileys Irish Cream, oil and vanilla. Set aside
In the bowl of your mixer, add the softened butter and mix at medium speed until smooth. Gradually add the sugar and continue to mix on medium speed 3 to 5 minutes until lightened in color and fluffy.
Add the eggs one at a time, mixing until the yellow of the yolk disappears.
Alternately, add the flour mixture and buttermilk mixture, beginning and ending with the dry ingredients (3 additions of dry and 2 of wet).
Do not mix above medium speed or over mix the batter.
Bake at 350 degrees for 25 to 30 minutes or until a toothpick inserted in the center comes out clean or with just a few crumbs attached. Let cool 5 to 10 minutes and turn out of pan.